Details

The general expression for a Faradaic current density is:

, , , , , ,

with the limiting cases

(Butler–Volmer, electron transfer control),

(Nernstian system, mass transport control).

[1] V. G. Levich, Physicochemical Hydrodynamics, 2nd ed., Englewood Cliffs, NJ: Prentice-Hall, Inc., 1962.

[2] A. J. Bard and L. R. Faulkner, Electrochemical Methods, New York: John Wiley & Sons, 2001.

[3] J.-P. Diard, C. Montella, and B. Le Gorrec, Cinétique Electrochimique, Paris: Hermann, 1996.